Group 18 Elements

Chemistry
NEET UG
Version 1Updated 22 Mar 2026

Group 18 elements, commonly known as the noble gases, are a unique family in the periodic table characterized by their exceptional chemical inertness under normal conditions. This inertness stems from their completely filled valence electron shells (ns2np6ns^2np^6 configuration, or 1s21s^2 for Helium), which makes them highly stable and reluctant to gain, lose, or share electrons. Comprising Helium (He…

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  • Electronic Configuration:ns2np6ns^2np^6 (except He: 1s21s^2).
  • Inertness:Due to stable, filled valence shell.
  • Ionization Enthalpy (IE):Very high, decreases down group.
  • Electron Gain Enthalpy (EGE):Highly positive (unfavorable).
  • Boiling Points:Very low, increases down group (due to increasing London forces).
  • Physical State:Monoatomic gases, colorless, odorless, tasteless.
  • Xenon Compounds:XeF2_2 (linear, sp3dsp^3d), XeF4_4 (square planar, sp3d2sp^3d^2), XeF6_6 (distorted octahedral, sp3d3sp^3d^3), XeO3_3 (pyramidal, sp3sp^3), XeOF4_4 (square pyramidal, sp3d2sp^3d^2).
  • Uses:He (cryogenics, diving), Ne (neon signs), Ar (inert atmosphere, bulbs), Kr (flash lamps), Xe (high-intensity lamps), Rn (radiotherapy).

To remember the order of noble gases and their increasing boiling points: Heavy New Army Kry Xenophobes Really Need. (He, Ne, Ar, Kr, Xe, Rn). For Xenon compounds and their shapes, visualize the central Xe atom and count electron pairs for VSEPR: 'Two Fs, Linear; Four Fs, Square; Six Fs, Distorted Octa; Three Os, Pyramidal; Four Fs and One O, Square Pyramidal.'

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