Physics

Surface Energy and Surface Tension

Capillarity

Physics
NEET UG
Version 1Updated 23 Mar 2026

Capillarity, often referred to as capillary action, is a phenomenon where a liquid spontaneously rises or falls in a narrow tube, known as a capillary tube, or porous material. This behavior is a direct consequence of the interplay between the cohesive forces within the liquid (attraction between liquid molecules) and the adhesive forces between the liquid and the solid surface (attraction between…

Quick Summary

Capillarity is the phenomenon of a liquid rising or falling in a narrow tube, driven by the interplay of surface tension, cohesive forces (liquid-liquid attraction), and adhesive forces (liquid-solid attraction).

When adhesive forces dominate, the liquid wets the surface, forms a concave meniscus, and rises (e.g., water in glass, θ<90\theta < 90^\circ). When cohesive forces dominate, the liquid doesn't wet, forms a convex meniscus, and falls (e.

g., mercury in glass, θ>90\theta > 90^\circ). The height of rise or fall (hh) is given by Jurin's Law: h=2Tcosθrρgh = \frac{2T\cos\theta}{r\rho g}, where TT is surface tension, θ\theta is the angle of contact, rr is the tube radius, ρ\rho is liquid density, and gg is acceleration due to gravity.

Key factors influencing capillarity are the tube's radius (inversely proportional), liquid's surface tension (directly proportional), and angle of contact. This principle is crucial in plant physiology, ink absorption, and various industrial processes.

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Key Concepts

Angle of Contact and Wetting

The angle of contact (θ\theta) is a critical parameter that dictates the nature of capillary action. It's…

Jurin's Law and its Dependencies

Jurin's Law, h=2Tcosθrρgh = \frac{2T\cos\theta}{r\rho g}, is the mathematical core of capillarity. It highlights that…

Effect of Insufficient Tube Length

A common misconception is that if a capillary tube is too short for the calculated rise, the liquid will…

  • Capillarity:Rise/fall of liquid in narrow tubes due to surface tension, cohesive, and adhesive forces.
  • Jurin's Law:h=2Tcosθrρgh = \frac{2T\cos\theta}{r\rho g}
  • $T$Surface Tension (N/m)
  • $\theta$Angle of Contact

- Acute (θ<90\theta < 90^\circ): Rise, concave meniscus, wetting (e.g., water/glass) - Obtuse (θ>90\theta > 90^\circ): Fall, convex meniscus, non-wetting (e.g., mercury/glass) - 9090^\circ: No action, flat meniscus

  • $r$Radius of tube (m) (h1/rh \propto 1/r)
  • $\rho$Density of liquid (kg/m3^3) (h1/ρh \propto 1/\rho)
  • $g$Acceleration due to gravity (m/s2^2) (h1/gh \propto 1/g)
  • Inclined Tube:Vertical height hh remains same, length along tube L=h/cosαL = h/\cos\alpha (where α\alpha is angle with vertical).
  • Insufficient Length:Liquid rises to top, meniscus flattens (radius of curvature increases), no overflow.

How Tall Can Radius Drop Gravity? (H = 2TCosθ\theta / RDG)

  • Height (hh) is proportional to:
  • Tension (TT)
  • Cosine of angle of contact (cosθ\cos\theta)
  • Inversely proportional to:
  • Radius (rr)
  • Density (ρ\rho)
  • Gravity (gg)
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