Chemistry·MCQ Practice

van der Waals Equation — MCQ Practice

NEET UG
Version 1Updated 22 Mar 2026

Interactive MCQ Practice

Test your knowledge. Click “Solve” to reveal options, select your answer, then check the result. 6 questions available.

Q1medium

For a real gas, the van der Waals equation is given by (P+an2V2)(Vnb)=nRT(P + a\frac{n^2}{V^2})(V - nb) = nRT. Which of the following statements is INCORRECT regarding the constants 'a' and 'b'?

Q2easy

Which of the following gases would have the highest value of the van der Waals constant 'a'?

Q3easy

For 1,mole1,\text{mole} of a real gas, the van der Waals equation is (P+a/V2)(Vb)=RT(P + a/V^2)(V - b) = RT. If the gas behaves ideally, what would be the value of the compressibility factor (Z)?

Q4medium

Given the van der Waals constants for two gases: Gas A (a=0.21,atm L2mol2a = 0.21,\text{atm L}^2 \text{mol}^{-2}, b=0.017,L mol1b = 0.017,\text{L mol}^{-1}) and Gas B (a=3.59,atm L2mol2a = 3.59,\text{atm L}^2 \text{mol}^{-2}, b=0.043,L mol1b = 0.043,\text{L mol}^{-1}). Which gas is expected to be more easily liquefied and why?

Q5hard

At very high pressures, the van der Waals equation for 1 mole of a real gas can be approximated as P(Vb)=RTP(V-b) = RT. What does this approximation suggest about the behavior of the gas at very high pressures?

Q6medium

The critical temperature (TcT_c) for a gas is given by Tc=8a27RbT_c = \frac{8a}{27Rb}. Which of the following statements is true regarding the critical temperature and liquefaction?

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